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//Madame Popova is one of those figures who sits somewhere between true crime, folklore, and social nightmare. The story most often told places her in late imperial Russia, near Samara, where unhappy wives came to her with a problem the law often refused to solve: violent, cruel, or impossible husbands. Divorce was difficult, reputation mattered, and a woman trapped in a dangerous marriage had few clean exits. Popova allegedly offered a brutal one.
For a fee, she made husbands disappear.
Some accounts call her Alexe or Katherina Popova and claim she operated for decades, from the late 1870s until 1909. Her methods were said to be flexible: poison when silence was needed, weapons when speed mattered, hired killers when distance was safer. The number attached to her name is staggering — around 300 men — though it should be treated carefully, because much of her story comes through sensational crime retellings rather than clean archival evidence.
What makes the legend so disturbing is not only the body count. It is the moral confusion around her. Popova was not remembered as a woman killing for jewels, inheritance, or lovers. She was described as a woman who saw herself as a rescuer. In her version of justice, a husband who beat, terrorized, or trapped his wife had already forfeited his right to live.//

https://www.serialkillercalendar.com/Madame%20POPOVA.php